川北硅质岩型铼多金属矿铼的赋存状态

川北硅质岩型铼多金属矿是国内首次发现的铼矿床新类型,矿石中具有Re、Se、V、Mo等多种有价元素富集,综合利用价值较好.本次通过X射线荧光光谱分析(XRF)、X射线衍射(XRD)、能谱分析(EDS)、电子探针(EPMA)、扫描电子显微镜(SEM)等多种手段开展矿石工艺矿物学及铼的赋存状态研究.结果 表明,矿石中主要矿物包括石英、伊利石、黄铁矿等,并含有大量碳质,Re、Se富集与S紧密相关,V富集与Si、A1紧密相关.黄铁矿电子探针分析结果显示,测点含硒平均值0.021％、铼含量平均值为0.024％,表明铼、硒主要以类质同象形态赋存于黄铁矿中.钒主要赋存于含钒伊利石等黏土矿物中.     

基于离散元模拟的二元颗粒柱坍塌特性研究

常见的地质灾害如滑坡、泥石流、岩崩等通常都涉及不同形状的颗粒物质运动,这些形状不同的颗粒又多具有不同的尺寸和含量。基于典型的颗粒柱坍塌试验,首先根据试验方法确定了离散元模拟所需的各项参数,然后采用随机多面体方法生成了可控制长细比的大颗粒,利用离散元法就不同大颗粒含量下形态变化对二元颗粒柱坍塌特性的影响开展研究,研究结果表明:(1)利用离散元法可以较好地重现室内试验中小球和多面体组成的二元颗粒系统的颗粒柱坍塌过程;(2)在不同长细比的不规则大颗粒和小球组成的二元颗粒柱系统中,当大颗粒含量高于临界含量值20%时,二元颗粒柱坍塌持续的时间随非球形大颗粒长细比的增加而增加;(3)在不同长细比的不规则大颗粒和小球组成的二元颗粒柱中,当大颗粒含量高于临界含量值20%时,在相同百分比的大颗粒含量下,大颗粒长细比的增加会提高大颗粒平均配位数以及降低颗粒的运动能力,大颗粒间形成更强的互锁作用,降低了颗粒柱的整体流动性,使其最终堆积高度更高、最大跑出距离更短以及更小的归一化动能峰值。(4)在不同长细比的不规则大颗粒和小球组成的二元颗粒柱中,小颗粒可以较为明显降低大颗粒间摩擦及互锁作用,增加流动性,降低大骨料形态对坍塌过程的影响。     

青海团宝山花岗岩年代学、地球化学特征及其地质意义

青海省团宝山花岗岩位于南祁连东段,侵位于古元古代化隆群中。为了解其侵位时代、岩体成因和产出构造环境,利用LA-ICP-MS锆石U-Pb定年和地球化学测试方法对团宝山花岗岩岩体样品进行分析。获得其锆石U-Pb年龄为(776±8) Ma;该岩体SiO₂、Al₂O₃和K₂O含量较高,而FeO^T、MgO和CaO含量较低,K₂O/Na₂O大于1,富集Rb、Th等元素,亏损Ba、Zr等元素,具明显的负铕异常,表现为轻稀土富集型稀土配分模式。该岩体为分异程度较高的过铝质钙碱性岩,具S型花岗岩特征,为晚元古代中期陆陆碰撞的产物;源岩为泥质岩或杂砂岩,侵位后在晋宁运动末期和加里东运动中期经历过岩浆热事件。     

四川旺苍大河坝浅变质岩型石墨矿床地球化学特征与成因分析

大河坝石墨矿是川北米仓山南缘石墨矿带新发现的大型显晶质石墨矿床。研究了该矿床的地质特征和矿石主量、微量及稀土元素地球化学特征,结果表明:含矿岩层为副变质岩,矿区石墨矿体原岩沉积于缺氧的还原环境,原岩为一套含碳质黏土质细—粉砂岩及含碳质泥灰岩组合。微量元素特征指示矿体原岩由近海陆源碎屑物沉积形成,沉积水体主要为盐度较低的、混合不均匀的淡水—半咸水。矿石ΣREE平均值为150×10^-6,与泥灰岩相近;δCe值平均为0.91,呈弱负异常,δEu值平均为0.67,呈负异常,具滨海潮坪相沉积特征。含矿岩石δ¹³C值为-21.4‰~-19.0‰,平均为-19.86‰,表明成矿碳质来源主要为有机碳,并混合了部分无机碳。矿床成因类型为沉积变质型,其变质作用可能包括多次区域变质作用并叠加了混合岩化作用。     

塔里木盆地玉尓吐斯组高频层序沉积充填演化特征及控烃作用

结合9个野外剖面和17口井,对塔里木盆地玉尔吐斯组沉积演化及其对烃源岩的制约作用进行了系统研究和分析。在精细对比后发现,塔里木盆地下寒武统玉尔吐斯组可分为2个三级层序(SQ1、SQ2)、5个四级层序(sq1—sq5),其中三级层序SQ1可分为3个四级层序,SQ2可分为2个四级层序。SQ1发生在寒武纪初期,海进速度较慢,影响范围相对局限,而SQ2的海进则相对迅速,影响范围较大。四级层序sq1发生在第一次海侵初期,水体浅,主要沉积紫红色白云岩、灰黑色砂屑白云岩,起填平补齐的作用;sq2、sq4发生在海侵—海退的转换时期,是两套深水的沉积,岩性以黑色泥岩、硅质泥岩和硅质岩为主,局部发育泥岩与条带状白云岩互层;sq3、sq5是海退过程中的浅水沉积,主要发育灰色白云岩和藻白云岩,局部有泥质夹层。利用Mn、Fe、Ti、Rb、K、Sr、Ba、Cu、U、V、Mo等元素及其比值进行沉积环境分析表明,sq2时期,水体深度大、盐度低、气候温暖湿润,有利于生物发育,并且其硫化缺氧的环境极其有利于有机质的保存;sq4时期,水体深度较大,盐度相对较小,气候相对温暖湿润,较为适合生物生存,并且其硫化缺氧夹次氧化的环境,较为适合有机质保存。高频海平面变化与沉积环境演化影响着玉尔吐斯组的烃源岩分布与品质,sq2时沉积的烃源岩品质优于sq4,但是其分布范围小于sq4。     

西湖凹陷杭州斜坡构造差异及其对成藏的影响

杭州斜坡是西湖凹陷油气勘探的新区,构造特征的研究是开展石油地质条件研究的基础。通过对杭州斜坡的结构、主控断裂的演化及其对油气运移控制作用的分析,探讨了斜坡结构差异及其对油气成藏的影响。研究结果表明:杭州斜坡分为北段、中段和南段三个部分,中段断层走向为北北东向,单个断层的延伸长度小但数量多,存在倾向东和倾向西的顺向断层和反向断层。迎翠轩主断裂在平湖组沉积时期持续活动,杭州斜坡中段在平湖组中段下部沉积时期断层活动最强,最大落差达800 m。迎翠轩主断层走向变化、断层两侧砂岩含量和岩性反演结果表明,杭州斜坡中段断层上升盘的砂体发育程度较北段差,封堵性优于北段。关键成藏期(23 Ma和12 Ma)杭州斜坡中段处在有利的油气运移通道之上,迎翠轩主断裂中段在15 Ma后基本不活动,有利于下降盘的油气聚集。     

基于水合物指示因子的地震识别方法

速度是水合物勘查的重要参数,但是速度的影响因素众多,给高精度识别水合物带来一定困难。水合物储层岩石物理是研究多种因素对速度影响的有效手段之一。考虑到水合物储层未固结等特征,本文采用SCA-DEM模型,重点对比了孔隙度、饱和度等对纵横波速度以及AVO特征的影响,并构建了一种新的水合物指示因子,消除了由于孔隙变化带来的假异常。岩石物理分析表明该指示因子与水合物饱和度具有很高的相关性。然后,推导得到了基于水合物指示因子的地震反射特征方程,并基于该方程反演得到了水合物指示因子,反演结果与实际钻探结果吻合较好,表明该方法具有一定的实用性以及科学性。     

Distribution Prediction of Middle-deep Lacustrine Source Rocks in Eocene Wenchang Formation in the Kaiping Sag,Pearl Mouth Basin

Oil and gas shows are rich in drilling wells in Kaiping sag,however,large oilfield was still not found in this area.For a long time,it is thought that source rocks were developed in the middle-deep lacustrine facies in the Eocene Wenchang Formation,while there is no source rocks that in middle-deep lacustrine facies have been found in well.Thickness of Wenchang Formation is big and reservoirs with good properties could be found in this formation.Distribution and scale of source rock are significant for further direction of petroleum exploration.Distribution characterization of middle-deep lacustrine facies is the base for source rock research.Based on the sedimentary background,fault activity rate,seismic response features,and seismic attributes were analyzed.No limited classification method and multi-attributes neural network deep learning method were used for predicting of source rock distribution in Wenchang Formation.It is found that during the deposition of lower Wenchang Formation,activity rate of main fault controlling the sub sag sedimentation was bigger than 100 m/Ma,which formed development background for middle-deep lacustrine facies.Compared with the seismic response of middle-deep lacustrine source rocks developed in Zhu I depression,those in Kaiping sag are characterized in low frequency and good continuity.Through RGB frequency decomposition,areas with low frequency are main distribution parts for middle-deep lacustrine facies.Dominant frequency,instantaneous frequency,and coherency attributes of seismic could be used in no limited classification method for further identification of middle-deep lacustrine facies.Based on the limitation of geology knowledge,multi-attributes of seismic were analyzed through neural network deep learning method.Distribution of middle-deep lacustrine facies in the fourth member of Wenchang Formation is oriented from west to east and is the largest.Square of the middle-deep lacustrine facies in that member is 154 km²and the volume is 50 km³.Achievements could be bases for hydrocarbon accumulation study and for exploration target optimization in Kaiping sag.     

U-Pb Zircon and Re-Os Molybdenite Geochronology of theW-Mo Mineralized Region of South Qinling,China, andtheir Tectonic Implications

A W-Mo mineralized region is located along the northern margin of the South Qinling tectonic belt of China. WMo mineralization occurs mainly in Cambrian–Ordovician clastic and carbonate rocks, and the ore bodies are structurally controlled by NW–SE-and NNE–SSW-striking faults. Evidence for magmatism in the area is widespread and is dominated by intermediate–felsic intrusives or apophyses, such as the Dongjiangkou, Yanzhiba, Lanbandeng, and Sihaiping granitic bodies. Quartz-vein-type mineralization and fault-controlled skarn-type mineralization dominate the ore systems, with additional enrichment in residual deposits. At present, there are few or insufficient studies on(1) the age of mineralization,(2) the relationship between intermediate–felsic granite and W-Mo mineralization,(3) the source of ore-forming materials,and(4) the metallogenic and tectonic setting of the mineralized area. In this paper, we present geochronology results for numerous intrusive granitic bodies in the South Qinling tectonic belt. U-Pb zircon geochronology of the Lanbandeng monzogranite and Wangjiaping biotite monzogranite yields ages of 222.7 ± 2.3 and 201.9 ± 1.8 Ma, respectively. In contrast to the Late Triassic age of the Lanbandeng monzogranite, the age of the newly discovered Wangjiaping biotite monzogranite places it at the Triassic–Jurassic boundary. Re-Os molybdenite geochronology on the Qipangou W-Mo deposit yielded a model age of 199.7 ± 3.9 Ma, indicating the deposit formed in the early Yanshanian period of the Early Jurassic. Granitoid intrusions in the mineralized area are characterized by composite granite bodies that crystallized at ca.240–190 Ma. While there were multiple stages of intrusion, most occurred at 210–220 Ma, with waning magmatic activity at 200–190 Ma. The Re-Os age of molybdenite in the region is ca. 200–190 Ma, which may represent a newly discovered period of W-Mo metallogenesis that occurred during the final stages of magmatism. The heat associated with this magmatism drove ore formation and might have provided additional ore-forming components for metallogenesis(represented by the Wangjiaping biotite monzogranite). Ore materials in the mineralized area were derived from mixed crustal and mantle sources. Enrichment of the region occurred during intracontinental orogenesis in the late Indosinian–Yanshanian, subsequent to the main Indosinian collision. At this time, the tectonic environment was dominated by extension and strike-slip motion.     

Geochronology, Fluid Inclusions and Isotopic Characteristics of the Dongjun Pb-Zn-Ag Deposit, Inner Mongolia, NE China

The Dongjun Pb-Zn-Ag deposit in the northern part of the Great Xing’an Range (NE China) consists of quartz-sulfide vein-type and breccia-type mineralization, related to granite porphyry. Hydrothermal alteration is well-developed and includes potassic-silicic-sericitic alteration, phyllic alteration and propylitic alteration. Three stages of mineralization are recognized on the basis of field evidence and petrographic observation, demarcated by assemblages of quartz-pyrite-arsenopyrite (early stage), quartz-polymetallic sulfide (intermediate stage) and quartz-carbonate-pyrite (late stage). Zircon LA-ICP-MS U-Pb dating indicates that the granite porphyry was emplaced at 146.7 ± 1.2 Ma (Late Jurassic). Microthermometry and laser Raman spectroscopy shows that ore minerals were deposited in conditions of intermediate temperatures (175–359°C), low salinity (0.5–9.3 wt% NaCl eqv.) and low density (0.60–0.91 g/cm3). Ore-forming fluids were derived largely from magmatic hydrothermal processes, with late-stage addition of meteoric water, belonging to a H2O-NaCl-CO2 ± CH4 system. The δ34SV-CDT values range from 0.75‰ to 4.70‰. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values of the ore minerals are in the ranges of 18.240–18.371, 15.542–15.570, and 38.100–38.178, respectively. Data for the S and Pb isotopic systems indicate that the ore-forming metals and sulfur were derived from Mesozoic magma. Based on the geological characteristics and geochemical signatures documented in this study, we conclude that the Dongjun deposit is a mesothermal magmatic hydrothermal vein-type Pb-Zn-Ag deposit controlled by fractures and related to granite porphyry, in response to Late Jurassic tectonic–magmatic–hydrothermal activity. We further conclude that fluid immiscibility, fluid mixing and fluid-rock interactions were the dominant mechanisms for deposition of the ore-forming materials.